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Article info. : 2005; 2(4) (pp 244~337)
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Synthesis of Triphenylmethylphosphonium Chlorochoromate as A
Mild and Selective Reagent for Oxidation of Alcohols
A.R. Hajipoura,b,*, L. Khazdooza and A.E.
Ruohob
aPharmaceutical Research Laboratory, College of
Chemistry, Isfahan University of Technology, Isfahan 84156, Iran
bDepartment of Pharmacology, University of Wisconsin
Med. Sch. 1300 University Avenue, Madison, 53706-1532, WI, USA
(Received 4 September2005, Accepted 1November 2005)
Triphenylmethylphosphonium chlorochoromate was synthesized
from triphenylmethyl bromide and chromium(VI) oxide in HCl 6 N and used as an
efficient and selective reagent for oxidation of alcohols to their corresponding
aldehydes or ketones derivatives in refluxing acetonitrile in good to excellent
yields.
Keywords: Alcohols, Aldehydes, Ketones, Oxidation,
Triphenylmethylphosphonium chlorochoromate
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