New Reagent for a One-Step Synthesis of Gem-Chloronitro Compounds from Oximes

M.A. Zolfigol^a,,A. Khazaei^a,, E. Kolvari^b,, N. Koukabi^a and M. Gilandoust^a*

^aFaculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran
^bDepartment of Chemistry, Faculty of Science, Semnan University, Semnan, Iran

The use of chlorine bleach (5% NaOCl) for the halogenation-oxidation of oximes to gem-chloronitro compounds is reported. Chlorine bleach afforded satisfactory yields when employed alone either at room temperature or under ultrasonic irradiation.

Keywords: Chlorine bleach, Gem-chloronitro compounds, Halogenation, Oxidation, Ultrasonic

New Reagent for a One-Step Synthesis of Gem-Chloronitro Compounds from Oximes

M.A. Zolfigola,*, A. Khazaeia,*, E. Kolvarib,*, N. Koukabia and M. Gilandousta

aFaculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran bDepartment of Chemistry, Faculty of Science, Semnan University, Semnan, Iran

M.A. Zolfigol^a,,A. Khazaei^a,, E. Kolvari^b,, N. Koukabi^a and M. Gilandoust^a*

^aFaculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran
^bDepartment of Chemistry, Faculty of Science, Semnan University, Semnan, Iran