Current location: JICS Archive > Vol. 7 > No. 2 > Articles : 11
Synthesis, Spectroscopic, Thermal, Crystal Characterization and Biological Activity of {[Ni(phen)3][Ni(dipic)2]}2.17H2O (H2dipic:Pyridine-2,6-dicarboxylic Acid, Phen: 1,10-Phenanthroline)
A.T. Colaka, F. Colakb, O.Z. Yesilelc and E. Sahind
aDepartment of Chemistry, Faculty of Arts and Sciences, Dumlupinar University, Kütahya-Turkey
bDepartment of Biology, Faculty of Arts and Sciences, Dumlupinar University, Kütahya-Turkey
cDepartment of Chemistry, Faculty of Arts and Sciences, Eskisehir Osmangazi University Eskisehir-Turkey
dDepartment of Chemistry, Faculty of Arts and Sciences, Atatürk University, Erzurum-Turkey
The new {[Ni(phen)3][Ni(dipic)2]}2.17H2O (1) (phen = 1,10-phenanthroline, dipic = dipicolinate)) has been prepared and characterized by elemental analysis, IR, UV-Vis, magnetic measurement and single crystal X-ray diffraction. The complex consists of two tris(1,10-phenanthroline)nickel(II) cations, two bis(dipicolinato)nickelate(II) anions and seventeen uncoordinated water molecules. The Ni(II) complex crystallizes in the triclinic space group P-1.The complex consisting of cation has distorted octahedral coordination by three bidentate phen ligands. In the complex anion, each dipic ligand simultaneously exhibits tridentate coordination modes through N atom of pyridine ring and oxygen atoms of the carboxylate groups. The crystal packing of 1 is a composite of intermolecular hydrogen bonding, π-π and C-H∙∙∙π interactions. The complex has also been investigated in terms of biological activity and it showed high activity against S. aureus fromGram positive bacteria and C. albicans from yeast tested.
Keywords: Dipicolinato complex, 1,10-Phenanthroline complex, Nickel(II) complex, Antimicrobial activity
